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The CH (Coal-hydrogen) compression tolerance depends from it's molecular chain, The long opened chain paraffin burns faster, but the iso-octane and the iso-parafin is shorter and diversified so it's better to arrest knocking, benzene + ciklohexan has a very strong bonding so they can cope the high temperature + pressure, they don't knocking! And for example alcohol burns very slow that's why you can use it on extremly high compression ratios!.